14816
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14816
Fluka
1,1′-Bis(diphenylphosphino)ferrocene
purum, ≥97.0% (C)
| Synonym: | 1,1′-Ferrocenebis(diphenylphosphine), 1,1′-Ferrocenediyl-bis(diphenylphosphine) |
| CAS Number: | 12150-46-8 |
| Linear Formula: | C34H28FeP2 |
| Molecular Weight: | 554.38 |
| MDL number: | MFCD00001422 |
| PubChem Substance ID: | 24848885 |
Description
| Other Notes | Transition metal complexes are efficient catalysts for the cross-coupling of Grignard reagents with organic halides and related compounds1,2,3 |
Properties
| grade | purum |
| assay | ≥97.0% (C) |
| mp | 181-182 °C (dec.)(lit.) |
| 181-183 °C (dec.) | |
| storage temp. | 2-8°C |
Safety
| Personal Protective Equipment | Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter |
| Safety Statements | 22-24/25 |
| WGK Germany | 3 |
Related Products
| Replaced by | 177261, 1,1′-Bis(diphenylphosphino)ferrocene |
References
| Cited Reference | 1. T. Hayashi et al. J. Am. Chem. Soc. 106, 158, (1984) |
| 2. J. Organomet. Chem. 285, 359, (1985) | |
| 3. N. Miyaura et al. J. Am. Chem. Soc. 111, 314, (1989) | |
| reference | Corp MSDS 1 (1), 433:D / FT-IR 2 (3), 4575:C / FT-IR 1 (2), 1154:B / FT-NMR 1 (3), 772:B / IR-Spectra (2), 1337:C / IR-Spectra (3), 1564:H / RegBook 1 (2), 3127:H / Structure Index 1, 495:B:1 |
